Skip to main content


Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II) CAS#: 506417-41-0
IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data

Identification

Product NameDichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II) IUPAC Namedichlororuthenium;2-diphenylphosphanylethanamineMolecular StructureCAS Registry Number 506417-41-0Synonyms506417-41-0Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)Dichlorobisruthenium(II)dichlororuthenium;2-diphenylphosphanylethanamineSCHEMBL1767611DTXSID30584787MFCD07782004AKOS015900275DB-216527F728762-(Diphenylphosphanyl)ethanamine-dichlororuthenium (2:1)dichlorobisruthenium (ii)2-(Diphenylphosphanyl)ethan-1-amine--dichlororuthenium (2/1)Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II), 95%DICHLOROBISRUTHENIUMMolecular FormulaC28H32Cl2N2P2RuMolecular Weight630.5InChIInChI=1S/2C14H16NP.2ClH.Ru/c2*15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;;;/h2*1-10H,11-12,15H2;2*1H;/q;;;;+2/p-2InChI KeyBJNVYFXBTNBKRU-UHFFFAOYSA-LSMILESC1=CC=C(C=C1)P(CCN)C2=CC=CC=C2.C1=CC=C(C=C1)P(CCN)C2=CC=CC=C2.ClCl

Patent InformationPatent IDTitlePublication DateUS2018/312454PROCESS FOR THE PREPARATION OF DEUTERATED ETHANOL FROM D22018

Physical Data

AppearanceYellow powder

Spectra

Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Frequency (NMR Spectroscopy), MHzChemical shifts31Pdichloromethane-d227161.839Chemical shifts31Pdichloromethane-d227161.8Chemical shifts, Spectrum31P1,4-dioxane-d830162

Route of Synthesis (ROS)

Route of Synthesis (ROS) of Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II) CAS 506417-41-0

ConditionsYieldIn toluene at 100℃; for 6h; Glovebox; Schlenk technique;Experimental Procedure2 0Preparation of (2)In a glove box, (0.25 mmol) was added to a schlenk flask equipped with a magnetic stir bar. The flask was then attached to a schlenk line and 3.4 mL of freshly distilled toluene added. The mixture was then rapidly stirred. A 1.7 mL toluene solution of Ph2PCH2CH2NH2, (0.50 mmol) in an NMR tube was then added via a cannula. Any residue in the NMR tube and cannula was washed into the flask with 1.7 mL of toluene. The light yellow mixture was then heated at 100° C. for 6 h. The yellow suspension that resulted was allowed to cool to RT before collecting the precipitate by filtration under Argon. The precipitate was then washed with 10.0 mL portions of toluene, three times (until colorless). The yellow solid was then dried in vacuo. Yield: 90%. Note: Excessive scraping of the product should be minimised to prevent the build-up of static electricity90%In toluene at 100℃; for 6h; Schlenk technique;90%

Safety and Hazards

GHS Hazard StatementsNot Classified

Other Data

DruglikenessLipinski rules componentMolecular Weight630.499HBA2HBD0Matching Lipinski Rules2Veber rules componentPolar Surface Area (PSA)0Rotatable Bond (RotB)4Matching Veber Rules2

Use PatternDichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II) CAS#: 506417-41-0 is primarily used as a homogeneous catalyst in hydrogenation, isomerization, and carbon–carbon bond-forming reactions. https://www.chemwhat.com/dichlorobis2-diphenylphosphinoethyla-cas-506417-41-0/

Comments

Post a Comment

Popular posts from this blog

BCB (Benzocyclobutene): — Watson International Enables the Transition from Concept to Scalable Application

Benzocyclobutene (BCB) is an organic compound with a rigid molecular structure composed of a conjugated benzene ring and a four-membered ring. Its excellent thermal stability and electrical properties have made it a highly promising candidate for next-generation electronic materials. Historically, its industrial adoption has been constrained by high production costs, complex purification processes, and limited output. However, with growing demand in high-end applications and recent advances in upstream technology, BCB is now poised for industrial-scale deployment. Material Properties and Structural Advantages BCB (C₈H₈) is a non-polar molecule, free of ester, carboxyl, or amide groups, giving it excellent dielectric properties and low moisture absorption. Its dielectric constant (Dk) and dissipation factor (Df) remain stable across wide temperature and frequency ranges—key metrics for ensuring signal integrity in high-frequency, high-speed communication systems. Unlike conventional m...
Post a Comment
Read more

Overcoming the "Choke Points" in Semaglutide Side Chain Synthesis with Core Technologies to Enable Efficient GLP-1 Drug Manufacturing

Semaglutide, a groundbreaking product in the GLP-1 drug class, owes its extended half-life and enhanced receptor affinity largely to its unique side chain, Ste-Glu-AEEA-AEEA-OSU (CAS: 1169630-40-3) . This side chain covalently modifies the peptide backbone, significantly improving pharmacokinetics and therapeutic performance. However, its complex structure presents two critical synthetic challenges: Precise Assembly of Repetitive AEEA Units: The side chain features consecutive AEEA (aminoethoxyethoxyacetic acid) units, which require stepwise coupling via highly activated intermediates (e.g., AEEA-AEEA). Any impurities or deviations compromise downstream reaction efficiency and may trigger irreversible byproducts. Stereochemistry and Stability of Glutamic Acid (Glu): The glutamic acid component must maintain strict L-configuration, and its carboxyl groups require directional protection (e.g., OtBu) to preserve biological activity. Leveraging deep expertise in peptide chemistry a...
Post a Comment
Read more

Empowering Innovation: ChemWhat's Organic Optoelectronic Ecosystem (Video)

A standout component of this lineup is the Fullerene C60 derivative, PC61BM. Widely recognized as a benchmark material, PC61BM plays a pivotal role not only in Organic Solar Cells (OSCs) but also in Perovskite Solar Cells (PSCs), where it functions as a highly efficient Electron Transport Layer (ETL) and grain boundary passivator. To address the varied requirements of universities, R&D centers, and commercial manufacturers, ChemWhat has standardized this product into two distinct purity levels: 99.5% for general research and 99.9% for high-precision device fabrication.
Post a Comment
Read more