Skip to main content


(4-Methylphenyl) iodonium hexafluorophosphate CAS#: 344562-80-7
IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data

Identification

Product Name(4-Methylphenyl) iodonium hexafluorophosphateIUPAC Name(4-methylphenyl)-iodanium;hexafluorophosphateMolecular StructureCAS Registry Number 344562-80-7Synonyms344562-80-7Iodonium, (4-methylphenyl)-, hexafluorophosphate(1-)DTXSID7074905Iodonium, (4-methylphenyl)(4-(2-methylpropyl)phenyl)-, hexafluorophosphate(1-)Iodonium, (4-methylphenyl)(4-(2-methylpropyl)phenyl)-, hexafluorophosphate(1-) (1:1)Iodonium, (4-methylphenyl)-, hexafluorophosphate(1-) (1:1)DTXCID8038859(4-Methylphenyl) iodonium hexafluorophosphate(4-Isobutylphenyl)(p-tolyl)iodonium hexafluorophosphate(V)(4-methylphenyl)-iodanium;hexafluorophosphateSCHEMBL29351331YNDYCGZWQZEBCS-UHFFFAOYSA-NMFCD21604561DB-327830NS00078576G70508(4-methylphenyl)iodonium hexafluorophosphate(4-Isobutylphenyl)(p-tolyl)iodonium Hexafluorophosphate (ca. 70% in Propylene Carbonate)(4-methylphenyl)iodanium; hexafluoro--phosphanuide(4-methylphenyl)iodanium; hexafluoro-lambda-phosphanuide(4-Isobutylphenyl)(4-methylphenyl)iodonium Hexafluorophosphate (ca. 70% in Propylene Carbonate)Molecular FormulaC17H20F6IPMolecular Weight496.21InChIInChI=1S/C17H20I.F6P/c1-13(2)12-15-6-10-17(11-7-15)18-16-8-4-14(3)5-9-16;1-7(2,3,4,5)6/h4-11,13H,12H2,1-3H3;/q+1;-1InChI KeyYNDYCGZWQZEBCS-UHFFFAOYSA-NSMILESCC1=CC=C(C=C1)C2=CC=C(C=C2)CC(C)C.F(F)(F)(F)(F)F

Patent InformationPatent IDTitlePublication DateWO2023/195774DIPHENYLIODONIUM SALT FOR PHOTOINITIATOR AND PREPARATION METHOD THEREFOR2023

Physical Data

AppearanceColorless to yellowish liquid

Spectra

Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Chemical shifts1Hchloroform-d1

Description (IR Spectroscopy)Bands, Spectrum

Route of Synthesis (ROS)

Route of Synthesis (ROS) of (4-Methylphenyl) iodonium hexafluorophosphate CAS 344562-80-7

ConditionsYieldStage #1: 1-phenyl-2-methylpropane; 4-Iodotoluene With sodium persulfate; toluene-4-sulfonic acid at 20℃; for 20h;Stage #2: With potassium hexafluorophosphate for 10h;Experimental Procedure1-4 Example 4(1) 23.7 g of p-toluenesulfonic acid, 11.5 g of sodium persulfate, 10 g of p-iodotoluene and 7.2 g of isobutylbenzene were added to a reaction kettle in sequence and reacted at room temperature for 20 hours;(2) After adding 14 g of potassium hexafluorophosphate to the reaction solution obtained in step (1), the reaction was continued for 10 hours, washed twice with water and petroleum ether respectively, and concentrated to obtain a yellow viscous liquid with a yield of 87% and a purity of 99.27%.87%

Safety and Hazards

Pictogram(s)SignalDangerGHS Hazard StatementsH302 (100%): Harmful if swallowed H317 (100%): May cause an allergic skin reaction H318 (100%): Causes serious eye damage H373 (100%): May causes damage to organs through prolonged or repeated exposure H400 (100%): Very toxic to aquatic life H410 (100%): Very toxic to aquatic life with long lasting effects Precautionary Statement CodesP260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P354+P338, P317, P319, P321, P330, P333+P317, P362+P364, P391, and P501

Other Data

DruglikenessLipinski rules componentMolecular Weight496.214HBA0HBD0Matching Lipinski Rules3Veber rules componentPolar Surface Area (PSA)0Rotatable Bond (RotB)4Matching Veber Rules2

Use Pattern4-Isobutylphenyl-4'-methylphenyliodonium hexafluorophosphate CAS 344562-80-7 is the most commonly used cationic photoinitiator, which can be sensitized by ITX and DETX to achieve longer absorption (LED curing) https://www.chemwhat.com/4-methylphenyl-4-2-methylpropylphenyl-iodonium-hexafluorophosphate-cas-344562-80-7/

Comments

Post a Comment

Popular posts from this blog

Watson's PDHP CAS 34562-31-7 The Secret to Light Yellow Liquid Appearance

In the competitive world of chemical manufacturing, maintaining consistency and meeting precise specifications are essential for success. One compound that highlights these principles is 3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine, commonly known as PDHP, with the CAS number 34562-31-7. PDHP is a versatile compound utilized in various industrial applications, including rubber additives and catalytic processes. Among its many attributes, Watson’s ability to consistently produce PDHP as a light yellow liquid stands out, especially in industries where the appearance of the final product is crucial. PDHP serves a vital role in several industrial sectors. In the rubber industry, it functions as an additive that enhances the durability and longevity of rubber products. PDHP’s properties help improve the stability of rubber, making it more resistant to environmental wear and tear. Additionally, in catalysis, PDHP’s structure allows it to act as an effective ligand or catalyst precurso...
Post a Comment
Read more
IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product Namemethylammonium iodideIUPAC Namemethylazanium;iodide Molecular StructureCAS Registry Number 14965-49-2MDL NumberMFCD28100833SynonymsMethylammonium iodide14965-49-2methylazanium;iodideEINECS 239-037-4methylazanium iodideMethanamine, hydriodideMethyl ammonium iodideMethylamine.hydriodicacidSCHEMBL1534750Methylammonium Iodide, anhydrousDB-221235NS00086090Molecular FormulaCH6INMolecular Weight158.97InChIInChI=1S/CH5N.HI/c1-2;/h2H2,1H3;1HInChI KeyLLWRXQXPJMPHLR-UHFFFAOYSA-N  Canonical SMILESC. Patent InformationPatent IDTitlePublication DateWO2023/180219A METHOD FOR SYNTHESIS OF HALIDE SALTS2023CN113845428Preparation method of perovskite material powder2021WO2018/169373METHOD OF PREPARING LUMINESCENT NANO-SHEET, LUMINESCENT NANO-SHEET MATERIAL, LUMINESCENT NANO-SHEET FILM, BACK LIGHT, AND LIQUID CRYSTAL DISPLAY APPARATUS2018WO2015/32748AMORPHOUS MATERIAL AND THE USE THEREOF2018 ...
Post a Comment
Read more
IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product NameNickel HydroxideIUPAC Namenickel;dihydrate Molecular StructureCAS Registry Number 12054-48-7EINECS Number235-008-5MDL NumberMFCD00011140Beilstein Registry NumberSynonyms12054-48-7AKOS015903693CS-0089243dihydroxynickelEC 235-008-5EINECS 235-008-5HSDB 1827LS-96321MFCD00011140Nickel dihydroxideNickel hydroxide (II)Nickel hydroxide (Ni(OH)2)Nickel hydroxide (ous)Nickel Hydroxide nanowireNickel(2+) hydroxidenickel(II) dihydroxideNickel(II) hydroxide, for analysisnickel;dihydrateNickelous hydroxideUNII-L8UW92NW6JMolecular FormulaH4NiO2Molecular Weight94.724 InChIInChI=1S/Ni.2H2O/h;2*1H2 InChI KeyAIBQNUOBCRIENU-UHFFFAOYSA-N  Canonical SMILESO.O.   Physical Data AppearanceGreen powder Spectra Description (IR Spectroscopy)Solvent (IR Spectroscopy)Temperature (IR Spectroscopy), °CBandssolid matrix-258 Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Comment (UV/VIS Spec...
Post a Comment
Read more