IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data
Identification
Product NameForMaMidiniuM IodideIUPAC Namemethanimidamide;hydroiodideMolecular StructureCAS Registry Number 879643-71-7SynonymsFormamidine Hydroiodide879643-71-7methanimidamide;hydroiodidemethanimidamide hydroiodideMFCD28369273Formamidine Hydroiodide (Low water content)ethanimidamide, hydriodide (1:1)Formamidinium IodidSCHEMBL7272878QHJPGANWSLEMTI-UHFFFAOYSA-NBS-43985SY057907F0974F1263T73028Formamidine Hydroiodide (99.99%, trace metals basis) Molecular FormulaCH5IN2 Molecular Weight171.969InChIInChI=1S/CH4N2.HI/c2-1-3;/h1H,(H3,2,3);1HInChI KeyQHJPGANWSLEMTI-UHFFFAOYSA-NIsomeric SMILESC(=N)N.I
Physical Data
AppearanceWhite to Yellow Solid
Spectra
Route of Synthesis (ROS)
Route of Synthesis (ROS) of 3-Aminopyridine CAS 462-08-8
ConditionsYieldIn 2-methoxy-ethanol; 1,2-dichloro-benzene at 100 - 150℃; Solvent;Experimental Procedure1-2; 1-2 Example 1: Numbers 7 and 8 of Table 1Mix 2ME (2-methoxy ethanol) and o-dichlorobenzene at a ratio of 9:1 or 8:2 in a 70ml vial to prepare 12ml of solvent, and then 3.44g (0.02mol) of FAI (Formamidinium Iodide) is dissolved in the solvent. Then, add 9.22 g (0.02 mol) of PbI2 (Lead Iodide) of the same equivalent to a 70 ml glass bottle in which FAI is dissolved, and mix for 3 hours until PbI2 is dissolved. After that, the solvent is stirred in the oil bath prepared at about 100 ~ 150°C for 10 to 30 minutes until the black powder (powder) of α-FAPbI3 falls as a precipitate. However, the black precipitate formation time may vary depending on the external temperature. Thereafter, the precipitate was filtered from the solvent under reduced pressure, and the filtered precipitate was dried on a hot plate prepared at 150° C. for 10 minutes to obtain black α-FAPbI3 in a yield of 85% or 90%. The above-described method can be similarly applied to numbers 9 and 10 of Table 1.
Safety and Hazards
Pictogram(s)SignalWarningGHS Hazard StatementsH302 (100%): Harmful if swallowed H315 (100%): Causes skin irritation H319 (100%): Causes serious eye irritation H335 (100%): May cause respiratory irritation Precautionary Statement CodesP260, P261, P264, P270, P271, P273, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P311, P312, P314, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P391, P403+P233, P405, and P501(The corresponding statement to each P-code can be found at the GHS Classification page.)
Other Data
TransportationUnder room temperature away from lightHS CodeStorageUnder room temperature away from lightShelf Life1 year
DruglikenessLipinski rules componentMolecular Weight171.969logP0.729HBA2HBD2Matching Lipinski Rules4Veber rules componentPolar Surface Area (PSA)49.87Rotatable Bond (RotB)0Matching Veber Rules2
Use PatternForMaMidiniuM Iodide CAS#: 879643-71-7 is a nitrogen-containing organic compound commonly used as an intermediate in chemical synthesis. And it can serve as a precursor for the preparation of active pharmaceutical ingredients (APIs) or other biologically active molecules. it can be involved in various reactions such as alkylation or the preparation of amine compounds in organic chemistry. https://www.chemwhat.com/formamidinium-iodide-cas-879643-71-7/
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