IdentificationPhysical DataSpectraRoute of SynthesisSafety and HazardsOther Data
Identifiers
Product Name12-MethacryloyldodeylphosphateIUPAC Name10-phosphonooxydecyl 2-methylprop-2-enoateMolecular StructureCAS Registry Number 85590-00-7Synonyms10-MDP;10-(meth)acryloyloxydecyl dihydrogen phosphate, 10-methacryloyloxydecyl dihydrogen phosphate, 10-methacryloyloxydecyl dihydrogenphosphate, (10-(methacryloyloxy)decyl) phosphate, MDP, 10-methacrylyloyloxydecyl dihydrogen phosphate, 10-(meth)acryloyloxydecyl dihydrogenphosphate Molecular FormulaC14H27O6P Molecular Weight322.33 InChiInChI=1S/C14H27O6P/c1-13(2)14(15)19-11-9-7-5-3-4-6-8-10-12-20-21(16,17)18/h1,3-12H2,2H3,(H2,16,17,18) InChI KeyCFKBCVIYTWDYRP-UHFFFAOYSA-NCanonical SMILESCC(=C)C(=O)OCCCCCCCCCCOP(=O)(O)O
Patent InformationPatent IDTitlePublication DateUS4539382Adhesive composition1985US2019/192386LIGHT CURABLE COMPOSITION2019WO2006/20760SELF-ADHESIVE COMPOSITIONS INCLUDING A PLURALITY OF ACIDIC COMPOUNDS2006US5733949Antimicrobial adhesive composition for dental uses1998US6353041Dental compositions2002
LiteratureTitlePublication NameEffect of a novel prime-and-rinse approach on short- and long-term dentin bond strength of self-etch adhesivesOral SciencesInteraction of ACP and MDP and its effect on dentin bonding performanceJournal of the Mechanical Behavior of Biomedical MaterialsPrime-and-rinse approach for improving the enamel micro-tensile bond strengths of self-etch adhesivesJournal of Adhesion Science and Technology
Physical Data
AppearanceLight yellow sticky liquid Boiling Point450.2°C at 760 mmHg Flash Point226.073°C Density1.137 g/ml Refractive Index 1.47@20℃
Spectra
Description (NMR Spectroscopy) Nucleus (NMR Spectroscopy) Chemical shifts, Spectrum 1H Chemical shifts, Spectrum 13CChemical shifts, Spectrum 31P12-Methacryloyldodeylphosphate CAS 85590-00-7 HNMR
Route of Synthesis
Route of Synthesis (ROS) of 12-Methacryloyldodeylphosphate CAS 85590-00-7
Conditions Yield With trimethylsilyl bromide at 20℃; for 26h; Time; Inert atmosphere;Experimental ProcedureThe molar ratio of the two is 1: 70, N2The trimethyldimethylsilane (TMSBr) was added dropwise to the three-necked flask at a molar ratio of methacryloyl decyl dimethoxy phosphate to trimethyl bromosilane (TMSBr) at room temperature, The dropping rate was 0.1 mL / min, and the molar ratio of methacryloyl decamethoxophosphate to allyltrimethylbromosilane was 1: 0.6 and allyl trimethylbromosilane was added dropwise To the three-necked flask, the dropping rate was 0.1 mL / min. After the dropwise addition, the reaction was carried out at room temperature for 24 hAfter completion of the reaction, the solvent was removed by a rotary evaporator, and the molar ratio of methacryloyl decamethoxophosphate to distilled water was 1: 8.4, stirred in distilled water at room temperature for 10 min,4HCO3After neutralization, then CHCl3After extraction, the aqueous phase was combined and lyophilized by a freeze dryer to obtain a white powder methacryloyl decyl dihydrogen phosphate in a yield of 83.2%.87%
Safety and Hazards
GHS Hazard StatementsNot ClassifiedSDS DownloadEnglish VersionGerman VersionDanish Version
Other Data
TransportationUnder the room temperature and away from lightHS Code291614Storage2-8°C away from light Shelf life6 monthsMarket priceUSD 3000/kg
Use PatternAcidic group-containing polymeric monomer Dental adhesive composition
Composition Speculation4-META10-13%10-MDP10-13%Distilet Water20%Acetone25-35%TEGDMA5%Glycerol Dimethacrylate15-25%Silanated Silica5-10%Stabilizer CAS#: 128-37-00.5-1%Photo Initiator CAS#: 75980-60-82.5-5%
https://www.chemwhat.com/12-methacryloyldodeylphosphate-cas-85590-00-7/
Identifiers
Product Name12-MethacryloyldodeylphosphateIUPAC Name10-phosphonooxydecyl 2-methylprop-2-enoateMolecular StructureCAS Registry Number 85590-00-7Synonyms10-MDP;10-(meth)acryloyloxydecyl dihydrogen phosphate, 10-methacryloyloxydecyl dihydrogen phosphate, 10-methacryloyloxydecyl dihydrogenphosphate, (10-(methacryloyloxy)decyl) phosphate, MDP, 10-methacrylyloyloxydecyl dihydrogen phosphate, 10-(meth)acryloyloxydecyl dihydrogenphosphate Molecular FormulaC14H27O6P Molecular Weight322.33 InChiInChI=1S/C14H27O6P/c1-13(2)14(15)19-11-9-7-5-3-4-6-8-10-12-20-21(16,17)18/h1,3-12H2,2H3,(H2,16,17,18) InChI KeyCFKBCVIYTWDYRP-UHFFFAOYSA-NCanonical SMILESCC(=C)C(=O)OCCCCCCCCCCOP(=O)(O)O
Patent InformationPatent IDTitlePublication DateUS4539382Adhesive composition1985US2019/192386LIGHT CURABLE COMPOSITION2019WO2006/20760SELF-ADHESIVE COMPOSITIONS INCLUDING A PLURALITY OF ACIDIC COMPOUNDS2006US5733949Antimicrobial adhesive composition for dental uses1998US6353041Dental compositions2002
LiteratureTitlePublication NameEffect of a novel prime-and-rinse approach on short- and long-term dentin bond strength of self-etch adhesivesOral SciencesInteraction of ACP and MDP and its effect on dentin bonding performanceJournal of the Mechanical Behavior of Biomedical MaterialsPrime-and-rinse approach for improving the enamel micro-tensile bond strengths of self-etch adhesivesJournal of Adhesion Science and Technology
Physical Data
AppearanceLight yellow sticky liquid Boiling Point450.2°C at 760 mmHg Flash Point226.073°C Density1.137 g/ml Refractive Index 1.47@20℃
Spectra
Description (NMR Spectroscopy) Nucleus (NMR Spectroscopy) Chemical shifts, Spectrum 1H Chemical shifts, Spectrum 13CChemical shifts, Spectrum 31P12-Methacryloyldodeylphosphate CAS 85590-00-7 HNMR
Route of Synthesis
Route of Synthesis (ROS) of 12-Methacryloyldodeylphosphate CAS 85590-00-7
Conditions Yield With trimethylsilyl bromide at 20℃; for 26h; Time; Inert atmosphere;Experimental ProcedureThe molar ratio of the two is 1: 70, N2The trimethyldimethylsilane (TMSBr) was added dropwise to the three-necked flask at a molar ratio of methacryloyl decyl dimethoxy phosphate to trimethyl bromosilane (TMSBr) at room temperature, The dropping rate was 0.1 mL / min, and the molar ratio of methacryloyl decamethoxophosphate to allyltrimethylbromosilane was 1: 0.6 and allyl trimethylbromosilane was added dropwise To the three-necked flask, the dropping rate was 0.1 mL / min. After the dropwise addition, the reaction was carried out at room temperature for 24 hAfter completion of the reaction, the solvent was removed by a rotary evaporator, and the molar ratio of methacryloyl decamethoxophosphate to distilled water was 1: 8.4, stirred in distilled water at room temperature for 10 min,4HCO3After neutralization, then CHCl3After extraction, the aqueous phase was combined and lyophilized by a freeze dryer to obtain a white powder methacryloyl decyl dihydrogen phosphate in a yield of 83.2%.87%
Safety and Hazards
GHS Hazard StatementsNot ClassifiedSDS DownloadEnglish VersionGerman VersionDanish Version
Other Data
TransportationUnder the room temperature and away from lightHS Code291614Storage2-8°C away from light Shelf life6 monthsMarket priceUSD 3000/kg
Use PatternAcidic group-containing polymeric monomer Dental adhesive composition
Composition Speculation4-META10-13%10-MDP10-13%Distilet Water20%Acetone25-35%TEGDMA5%Glycerol Dimethacrylate15-25%Silanated Silica5-10%Stabilizer CAS#: 128-37-00.5-1%Photo Initiator CAS#: 75980-60-82.5-5%
https://www.chemwhat.com/12-methacryloyldodeylphosphate-cas-85590-00-7/
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